Documento #582

Processato

Contenuto Testuale

Pd-Catalyzed Selective Remote Ring Opening of Polysubstituted Cyclopropanols.
The distant functionalization of ω-ene cyclopropanols is induced by a Pd-catalyzed Heck reaction triggering a "metal-walk" and selective ring-opening of the three-membered ring. This approach provides a new class of acyclic aldehydes possessing concomitantly a stereodefined double bond and a quaternary carbon stereocenter α to the carbonyl group.

Vettore Embedding

[-0.09382288, -0.006809483, -0.084417075, 0.00851766, 0.00695595, ... ]

Dimensioni 768 dim
Creato il 31/03/2026 15:19
Model

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