PRISMΔDB

Analyze how specific documents activate the features of the SAE. Select a dataset, a run and a document to begin.

Active Features

1519

0.0
Details List
#1027 Feature 1027
3.0
#1573 Feature 1573
2.9
#2105 Feature 2105
2.8
#886 Feature 886
2.7
#1690 Feature 1690
2.6
#1285 Feature 1285
2.5
#378 Feature 378
2.5
#1971 Feature 1971
2.5
#1009 Feature 1009
2.4
#351 Nanomaterial Synthesis and Properties
2.4
#1300 Feature 1300
2.4
#2593 Feature 2593
2.4
#1781 Feature 1781
2.3
#2216 Feature 2216
2.3
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2.3
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2.2
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2.1
#534 Feature 534
2.1
#2827 Feature 2827
2.1
#2992 Feature 2992
2.0
#1526 Feature 1526
2.0
#945 Feature 945
2.0
#316 Feature 316
1.9
#909 Feature 909
1.9
#2118 Feature 2118
1.9
#1358 Feature 1358
1.9
#331 Feature 331
1.8
#2766 Feature 2766
1.8
#2447 Feature 2447
1.8
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1.8
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1.7
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1.7
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1.7
#12 Feature 12
1.7
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1.7
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1.7
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1.7
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1.7
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1.6
#319 Feature 319
1.6
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1.6
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1.6
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1.6
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1.6
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1.6
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1.6
#2319 Feature 2319
1.6
#2450 Feature 2450
1.6
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1.6
#1379 Feature 1379
1.6
#1015 Feature 1015
1.6
#836 Feature 836
1.6
#2349 Feature 2349
1.6
#2819 Feature 2819
1.6
#1951 Feature 1951
1.6
#600 Feature 600
1.6
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1.5
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1.5
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1.5
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1.5
#3027 Feature 3027
1.5
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1.5
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1.5
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1.5
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1.5
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1.5
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1.5
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1.5
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1.5
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1.5
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.4
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1.3
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1.3
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1.3
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1.3
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1.3
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1.3
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1.3
#2925 Feature 2925
1.3
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1.3
#545 Feature 545
1.3
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1.3
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1.3
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1.3
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1.3
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1.3
#2200 Feature 2200
1.3
#3043 Feature 3043
1.3
#1800 Feature 1800
1.3
#2410 Feature 2410
1.3
#249 Feature 249
1.3
#743 Feature 743
1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
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1.2
#2012 Feature 2012
1.2
#2035 Feature 2035
1.2
#1085 Feature 1085
1.2
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1.2
#33 Feature 33
1.2
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1.2
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1.2
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1.2
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.1
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
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1.0
#2794 Feature 2794
1.0
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1.0
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1.0
#2341 Feature 2341
1.0
#2182 Feature 2182
1.0
#1955 Feature 1955
1.0
#3039 Feature 3039
1.0
#75 Feature 75
1.0
#1135 Feature 1135
1.0
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1.0
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1.0
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1.0
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1.0
#1938 Feature 1938
1.0
#2373 Feature 2373
1.0
#1576 Feature 1576
1.0
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1.0
#1501 Feature 1501
1.0
#1044 Feature 1044
1.0
#2215 Feature 2215
1.0
#2187 Feature 2187
1.0
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1.0
#2085 Feature 2085
1.0
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1.0
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1.0
#1352 Feature 1352
1.0
#404 Interactions and Mechanisms
1.0
#1221 Feature 1221
1.0
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1.0
#185 Feature 185
1.0
#709 Feature 709
1.0
#1325 Feature 1325
1.0
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1.0
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.9
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.8
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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0.7
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Document Content

Ideal CdSe/CdS Core/Shell Nanocrystals Enabled by Entropic Ligands and Their Core Size-, Shell Thickness-, and Ligand-Dependent Photoluminescence Properties.
This work explored possibilities to obtain colloidal quantum dots (QDs) with ideal photoluminescence (PL) properties, i.e., monoexponential PL decay dynamics, unity PL quantum yield, ensemble PL spectrum identical to that at the single-dot level, single-dot PL nonblinking, and antibleaching. Using CdSe/CdS core/shell QDs as the model system, shell-epitaxy, ligand exchange, and shape conversion of the core/shell QDs were studied systematically to establish a strategy for reproducibly synthesizing QDs with the targeted properties. The key synthetic parameter during epitaxy was application of entropic ligands, i.e., mixed carboxylate ligands with different hydrocarbon chain length and/or structure. Well-controlled epitaxial shells with certain thickness (∼3-8 monolayers of the CdS shells) were found to be necessary to reach ideal photoluminescence properties, and the size of the core QDs was found to play a critical role in determining both photophysical and photochemical properties of the core/shell QDs. Effects of shape of the core QDs were unnoticeable, and shape of the core/shell QDs only affected photophysical properties quantitatively. Surface ligands, amines versus carboxylates, were important for photochemical properties (antiblinking and antibleaching) but barely affected photophysical properties as long as entropic ligands (mixed carboxylate ligands with distinguishable hydrocarbon chain lengths) were applied during epitaxy. Chemical environment (in polymer or in air), coupled with surface ligands, determined photochemical properties of the core/shell QDs with a given core size and shell thickness.