Analyzer · Sparsifire

Analyze how specific documents activate the features of the SAE. Select a dataset, a run and a document to begin.

Dataset

SAE Model

Document

Active Features

1529

MIN ACTIVATION

0.0

Details List

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#708 Drug Resistance Mechanisms in Cancer

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#404 Interactions and Mechanisms

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#2171 Molecular and Cellular Biological Processes

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Document Content

Stereocontrolled access to isoprostanes via a bicyclo[3.3.0]octene framework.
We report a simple and highly stereocontrolled strategy toward the total synthesis of isoprostanes based on a bicyclic alpha,beta-epoxy ketone intermediate 6. Bicyclo[3.3.0]octene scaffold permitted stereodirection of reagents allowing stereoselective epoxidation, diastereoselective ketone reduction, and regioselective epoxide opening otherwise not accessible with a simple cyclopentene framework.

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